Photoenzymatic翻译
Web(photovoltaic在剑桥英语-中文(简体)词典的翻译 © Cambridge University Press) WebApr 5, 2024 · Herein, we described a photoenzymatic approach for the radical-mediated stereoselective hydrosulfonylation. Engineered variants of ene reductases provide efficient biocatalysts for this transformation, enabling to achieve a series of β-chiral sulfonyl compounds with high yields (up to 92%) and excellent e.r. values (up to 99:1).
Photoenzymatic翻译
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WebThe excellent photocatalytic performance is attributed to the unique photoenzymatic catalytic cascade system, heterointerface effect, good conductivity, and a wide sunlight response range of the PDI/CN heterojunction. This work provides an efficient strategy and a corresponding photocatalyst for the directional conversion of CO 2 to HCOOH. WebSustainable photochemical NADH regeneration and redox-enzymatic synthesis are accomplished by using CdS nanocrystals grown on the surface of SiO2 beads. CdS nanocrystals grown on SiO2 beads worked efficiently as a visible-light absorbing photocatalyst for in situNADH regeneration with high catalytic activity
WebMay 13, 2024 · Photoenzymatic cascades can be used for selective oxygenation of C−H-Bonds under mild conditions circumventing the hydrogen peroxide mediated … WebAug 16, 2024 · The free fatty acids were then, in a photoenzymatic step, decarboxylated into the C1-shortened alkanes using a recently described photodecarboxylase from Chlorella variabilis NC64A. This cascade …
WebAug 28, 2024 · Flavin-dependent “ene”-reductases can generate stabilized alkyl radicals when irradiated with visible light; however, they are not known to form unstabilized … WebSep 16, 2024 · DOI: 10.33774/chemrxiv-2024-955hf Corpus ID: 239046603; Photoenzymatic Synthesis of α-Tertiary Amines by Engineered Flavin-Dependent "Ene"-Reductases. @article{Gao2024PhotoenzymaticSO, title={Photoenzymatic Synthesis of $\alpha$-Tertiary Amines by Engineered Flavin-Dependent "Ene"-Reductases.}, author={Xin-Lian Gao and …
WebOct 8, 2024 · The photoenzymatic decarboxylation of fatty acids to alkanes is proposed as an alternative approach for the synthesis of biodiesel. By using a recently discovered photodecarboxylase from Chlorella variabilis NC64A (CvFAP) we demonstrate the irreversible preparation of alkanes from fatty acids and triglycerides. Several fatty acids …
WebJun 8, 2024 · Here we show a new-to-nature, visible-light-induced ene-reductase catalysed intermolecular radical hydroalkylation of terminal alkenes with readily available α-halo carbonyl compounds. This method provides an efficient approach to various carbonyl compounds bearing a γ-stereocentre with excellent yields and enantioselectivities (up to … diamond painting accessories australiaWebphotovoltaic翻译:光生伏打的。了解更多。 diamond painting accessories lightsWebDec 28, 2024 · Intermolecular C–C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent ‘ene’-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer … cir lat add inWebNov 14, 2024 · In conclusion, we have developed a general photoenzymatic platform to initiate and control reactions involving highly reactive NCRs, and by harnessing the power … cirkut wifeWebHere we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent 'ene'-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer complex that forms between an alkene, α-chloroamide, and flavin hydroquinone. diamond painting accessories on amazonWebphotosensitive翻译:感光的。了解更多。 The retina comprises numerous pigment cells and photoreceptors; the latter are easily modified flagellated cells, whose flagellum … diamond painting accessoiresWebT1 - Photoenzymatic Hydrogenation of Heteroaromatic Olefins Using ‘Ene’-Reductases with Photoredox Catalysts. AU - Nakano, Yuji. AU - Black, Michael J. AU - Meichan, Andrew J. AU - Sandoval, Braddock A. AU - Chung, Megan M. AU - Biegasiewicz, Kyle F. AU - Zhu, Tianyu. AU - Hyster, Todd K. diamond painting accessories canada